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Transient Imines as 'Next Generation' Directing Groups for the Catalytic Functionalisation of C-H Bonds in a Single Operation

Org. Biomol. Chem., 2018, Accepted ManuscriptDOI: 10.1039/C8OB00926K, Review ArticleSahra St John-Campbell, James A BullC-H Functionalisation promises a paradigm shift in synthetic planning. However, the additional steps often required to install and remove directing groups currently detracts from the efficiency. The strategy of reversible...The content of this RSS Feed (c) The Royal Society of Chemistry

Rapid and reversible hydrazone bioconjugation in cells without the use of extraneous catalysts

Org. Biomol. Chem., 2018, Accepted ManuscriptDOI: 10.1039/C8OB00946E, PaperRahul Nisal, Gregor P. Jose, Chitra Shanbhag, Jeet KaliaThe amenability of hydrazone linkages to disassemble via either hydrolysis in mildly acidic aqueous solutions or transimination upon treatment with amine nucleophiles renders them extremely attractive for applications in chemical...The content of this RSS Feed (c) The Royal Society of Chemistry

FeCl3/MeSO3H-Promoted Multicomponent Reactions Facile Synthesis of Structurally Diverse Furan Analogues

Org. Biomol. Chem., 2018, Accepted ManuscriptDOI: 10.1039/C8OB00942B, PaperZhiwei Chen, Xiangqing Chang, Xiongfei ZhangAn intriguing conversion of arylglyoxal, cyclic dicarbonyl compounds and phenols to diverse furan analogues under FeCl3 or MeSO3H catalysis is reported. Utilizing this synthetic protocol, a variety of furan analogues...The content of this RSS Feed (c) The Royal Society of Chemistry

Energy Transfer Chemiluminescence for Ratiometric pH Imaging

Org. Biomol. Chem., 2018, Accepted ManuscriptDOI: 10.1039/C8OB00972D, PaperWeiwei An, Ralph Mason, Alexander LippertChemiluminescence imaging offers a low background and high sensitivty approach to imaging analytes in living cells and animals. Intensity-based measurements have been developed, but require careful consideration of kinetics, probe...The content of this RSS Feed (c) The Royal Society of Chemistry

Hypermonins A and B, two 6-norpolyprenylated acylphloroglucinols with unprecedented skeletons from Hypericum monogynum

Org. Biomol. Chem., 2018, Accepted ManuscriptDOI: 10.1039/C8OB00650D, PaperXiaojiang Hao, Yanrong Zeng, Ping Yi, Wei Gu, Chunxia Xiao, Liejun Huang, Dongsong Tian, Hui Yan, Duozhi Chen, Chunmao YuanTwo new 6-norpolycyclic polyprenylated acylphloroglucinols (PPAPs), hypermonins A (1) and B (2), featuring an undescribed decahydroindeno[1,7-bc]furan ring system, were isolated from the leaves and twigs of Hypericum monogynum.

Base-Controlled Fe(Pc)-Catalyzed Aerobic Oxidation of Thiols for the Synthesis of S-S and S-P(O) Bond

Org. Biomol. Chem., 2018, Accepted ManuscriptDOI: 10.1039/C8OB00908B, CommunicationHai Huang, Jeffrey Ash, Jun Yong KangA Fe(Pc)-catalyzed aerobic oxidation of thiols for the synthesis of disulfide has been developed under mild reaction conditions. In addition, aerobic oxidative cross-dehydrogenative coupling (CDC) reaction of thiols with P(O)-H...The content of this RSS Feed (c) The Royal Society of Chemistry

Anti-Staphylococcal Biofilm Activity of Miconazoctylium Bromide

Org. Biomol. Chem., 2018, Accepted ManuscriptDOI: 10.1039/C8OB00897C, PaperJeremie Tessier, Mahmood Golmohamadi, Kevin J Wilkinson, Andreea R. SchmitzerWe designed and synthesized miconazole analogues containing a substituted imidazolium moiety. The structural modification of the miconazole led to a compound with high potency to prevent the formation and disrupt...The content of this RSS Feed (c) The Royal Society of Chemistry

Caged cyclopropenes for controlling bioorthogonal reactivity

Org. Biomol. Chem., 2018, Accepted ManuscriptDOI: 10.1039/C8OB01076E, CommunicationPratik Kumar, Ting Jiang, Sining Li, Omar Zainul, Scott T LaughlinBioorthogonal ligations have been designed and optimized to provide new experimental avenues for understanding biological systems.

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