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Radical selenylative cyclization of trifluoromethyl propargyl imines for the synthesis of trifluoromethyl- and seleno-azaspiro[4,5]-tetraenones and quinolines

Org. Biomol. Chem., 2022, Accepted ManuscriptDOI: 10.1039/D2OB02033E, CommunicationGuangming Wei, Jiajun Zhang, Haoyuan Wang, Zhengkai Chen, Xiao-Feng WuA radical selenylative cyclization of trifluoromethyl propargyl imines with diselenides for the regiodivergent construction of diversely functionalized azaspiro[4,5]-tetraenones and quinolines has been developed, which enable dual incorporation of CF3 and...The content of this RSS Feed (c) The Royal Society of Chemistry

A 4-state acid-base controlled molecular switch based on a host-guest system

Org. Biomol. Chem., 2022, Accepted ManuscriptDOI: 10.1039/D2OB01994A, PaperGaël De Leener, Diana Over, Olivia Reinaud, Ivan JabinA novel ZnII funnel complex that presents three phenol functions within the calix[6]arene macrocycle is described. Host-guest studies, monitored by 1H NMR spectroscopy, evaluate the impact of the replacement of...The content of this RSS Feed (c) The Royal Society of Chemistry

Cyrene: A Bio-based Solvent for the Mizoroki-Heck Reaction of Aryl Iodides

Org. Biomol. Chem., 2022, Accepted ManuscriptDOI: 10.1039/D2OB02012B, PaperNaya ?. Stini, Petros L Gkizis, Christoforos G KokotosThe development of greener and more sustainable methods, as well as the adaptation of already existing protocols to more environmentally friendly procedures, has become crucial for Organic Synthesis. The introduction...The content of this RSS Feed (c) The Royal Society of Chemistry

Arynes as Synthetic Linchpins Towards the Construction of Diversely Functionalized Natural Product Skeletons

Org. Biomol. Chem., 2022, Accepted ManuscriptDOI: 10.1039/D2OB01975B, Review ArticleR. Bharath Krishna, Shirin Hanna Moncy, Chithra MohanArynes are a privileged class of reactive intermediates in synthetic organic chemistry, and their unusual reactivities have been the subject of engrossing research interest. Recently, arynes-based synthetic innovations have been...The content of this RSS Feed (c) The Royal Society of Chemistry

Targeting tubulin C-terminal tail by charged small molecules

Org. Biomol. Chem., 2022, Accepted ManuscriptDOI: 10.1039/D2OB01910H, PaperShuo Li, Mattia Mori, Mingyan Yang, soumia elfazazi, Rafael Hortigüela, Peter Chan, Xinyue Feng, April L. Risinger, Zhi-You Yang, María A. Oliva, J. Fernando Diaz, Wei-Shuo FangThe disordered tubulin C-terminal tail (CTT), which possesses higher degree of heterogeneity, is the target for the interaction of many proteins and cellular components. Oppositely to the seven well-described binding...The content of this RSS Feed (c) The Royal Society of Chemistry

Palladium-Catalyzed Cascade Cyclization of Allenamide with 2-Iodoanilines to Access Functionalized Indoloquinolines

Org. Biomol. Chem., 2022, Accepted ManuscriptDOI: 10.1039/D2OB01770A, CommunicationWenzhe Geng, Hui Wang, Juan XI, Ruonan Jiang, Jintao Guo, Keqiang Jiao, Mengyao Tang, Qing Liu, Lizhi Zhang, Hui LiuA novel and efficient palladium-catalyzed cascade cyclization to indoloquinolines derivates in one pot has been developed by using allenamide derivates and 2-iodoanilines as the key building blocks. The process underwent...The content of this RSS Feed (c) The Royal Society of Chemistry

Redox-neutral rhodium(III)-catalyzed divergent synthesis of tetrasubstituted 1,3-enynes and alkynylated benzofurans

Org. Biomol. Chem., 2022, Accepted ManuscriptDOI: 10.1039/D2OB01800D, PaperXin Gong, Na Yu, Linghui Gu, Zheyu Li, Wenbo Ma, Fei ZhaoWith the assistance of the acetamido directing group (DG), a rhodium-catalyzed C?H alkenylation/DG migration cascade for the synthesis of tetrasubstituted 1,3-enynes from N-phenoxyacetamides and 1,3-diynes has been achieved in this...The content of this RSS Feed (c) The Royal Society of Chemistry

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