Sulfamides Direct Radical-Mediated Chlorination of Aliphatic C–H Bonds

Chem. Sci., 2019, Accepted ManuscriptDOI: 10.1039/C9SC03428E, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Melanie A Short, Mina F. Shehata, Matthew A. Sanders, Jennifer L. RoizenGiven the prevalence of aliphatic amines in bioactive small molecules, amine derivatives are opportune as directing groups. Herein, sulfamides serve as amine surrogates to guide intermolecular chlorine-transfer at ?-C(sp3) centers....The content of this RSS Feed (c) The Royal Society of Chemistry

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