Silyl-mediated photoredox-catalyzed Giese reaction: addition of non-activated alkyl bromides

  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'ad:0:aurora:http://slickfinder.com/content/silyl-mediated-photoredox-catalyzed-giese-reaction-addition-non-activated-alkyl-bromides' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = '', created = 1534694031, expire = -1, headers = '', serialized = 0 WHERE cid = 'ad:0:aurora:http://slickfinder.com/content/silyl-mediated-photoredox-catalyzed-giese-reaction-addition-non-activated-alkyl-bromides' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'counter:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = 'a:2:{s:7:\"subject\";s:7:\"Counter\";s:7:\"content\";s:335:\"<ul id=\"counter\"><li>Site Counter: 7,016,202</li><li>Unique Visitor: 333,619</li><li>Registered Users: 1</li><li>Unregistered Users: 0</li><li>Blocked Users: 0</li><li>Published Nodes: 285,247</li><li>Unpublished Nodes: 6,329</li><li>Server IP: 216.53.213.119</li><li>Your IP: 54.80.208.105</li><li>Since: 2014-07-03 13:09:52</li></ul>\";}', created = 1534694035, expire = -1, headers = '', serialized = 1 WHERE cid = 'counter:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'tribune:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = '', created = 1534694035, expire = -1, headers = '', serialized = 0 WHERE cid = 'tribune:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'tribune:1:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = '', created = 1534694035, expire = -1, headers = '', serialized = 0 WHERE cid = 'tribune:1:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'user:2:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = 'a:2:{s:7:\"subject\";s:9:\"Who\'s new\";s:7:\"content\";s:126:\"<div class=\"item-list\"><ul><li class=\"first last\"><a href=\"/users/admin\" title=\"View user profile.\">admin</a></li>\n</ul></div>\";}', created = 1534694035, expire = -1, headers = '', serialized = 1 WHERE cid = 'user:2:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'book:0:aurora:r.1:http://slickfinder.com/content/silyl-mediated-photoredox-catalyzed-giese-reaction-addition-non-activated-alkyl-bromides' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = 'a:2:{s:7:\"subject\";s:15:\"Book navigation\";s:7:\"content\";s:0:\"\";}', created = 1534694035, expire = -1, headers = '', serialized = 1 WHERE cid = 'book:0:aurora:r.1:http://slickfinder.com/content/silyl-mediated-photoredox-catalyzed-giese-reaction-addition-non-activated-alkyl-bromides' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'similar:0:aurora:r.1:http://slickfinder.com/content/silyl-mediated-photoredox-catalyzed-giese-reaction-addition-non-activated-alkyl-bromides' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = '', created = 1534694035, expire = -1, headers = '', serialized = 0 WHERE cid = 'similar:0:aurora:r.1:http://slickfinder.com/content/silyl-mediated-photoredox-catalyzed-giese-reaction-addition-non-activated-alkyl-bromides' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'simplead_block:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = '', created = 1534694035, expire = -1, headers = '', serialized = 0 WHERE cid = 'simplead_block:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'pagination:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = '', created = 1534694035, expire = -1, headers = '', serialized = 0 WHERE cid = 'pagination:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'recipe:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = 'a:2:{s:7:\"subject\";s:14:\"Newest Recipes\";s:7:\"content\";b:0;}', created = 1534694035, expire = -1, headers = '', serialized = 1 WHERE cid = 'recipe:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.

Chem. Sci., 2018, 9,6639-6646DOI: 10.1039/C8SC02253D, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Abdellatif ElMarrouni, Casey B. Ritts, Jaume BalsellsThe development of a conjugate addition reaction of non-activated alkyl bromides to Michael acceptors under visible-light photoredox catalysis is disclosed. A diverse set of alkyl bromides was successfully added to ?,?-unsaturated esters and amides. This transformation allowed access to a key intermediate of Vorinostat®, an HDAC inhibitor used to fight cancer and HIV.The content of this RSS Feed (c) The Royal Society of Chemistry

Powered by Drupal - Design by artinet

Drupal SEO