Room temperature olefination of methane with titanium-carbon multiple bonds

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Chem. Sci., 2018, 9,3376-3385DOI: 10.1039/C7SC05238C, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Takashi Kurogi, Joonghee Won, Bohyun Park, Oleksandra S. Trofymchuk, Patrick J. Carroll, Mu-Hyun Baik, Daniel J. MindiolaC-H activation of methane followed by dehydrocoupling at room temperature led ultimately to the formation of the olefin H2C[double bond, length as m-dash]CHtBu via the addition of redox-active ligands (L) such as thioxanthone or 2,2[prime or minute]-bipyridine (bipy) to (PNP)Ti[double bond, length as m-dash]CHtBu(CH3) (1).The content of this RSS Feed (c) The Royal Society of Chemistry

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