Rh-catalyzed regio-switchable cross-coupling of gem-difluorinated cyclopropanes with allylboronates to structurally diverse fluorinated dienes

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Chem. Sci., 2022, 13,12419-12425DOI: 10.1039/D2SC04118A, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yaxin Zeng, Hui Yang, Jiayi Du, Qin Huang, Guoliang Huang, Ying XiaRh-catalyzed regio-switchable cross-coupling reactions of gem-difluorinated cyclopropanes with allylboronates have been developed. Fluorinated 1,4-dienes, 1,5-dienes and 1,3-dienes are produced in good yields with excellent regioselectivity.The content of this RSS Feed (c) The Royal Society of Chemistry

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