Mechanistic investigation of cyclic ketene acetal radical ring-opening homo- and co-polymerization and preparation of PEO graft copolymers with tunable composition

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Polym. Chem., 2022, 13,5829-5840DOI: 10.1039/D2PY00986B, PaperYifeng Du, Yuhui Du, Stefano Lazzari, Tom Reimers, Rupert Konradi, Thomas W. Holcombe, E. Bryan CoughlinRadical ring-opening polymerization of cyclic ketene acetals (CKAs) led to homogeneous ester insertion during semi-batch reactions with N-vinyl pyrrolidone (NVP). Investigation of CKA radical transfer allowed for CKA–NVP graft copolymer preparation.The content of this RSS Feed (c) The Royal Society of Chemistry

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