Impact of the macrocyclic structure and dynamic solvent effect on the reactivity of a localised singlet diradicaloid with ?-single bonding character

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Chem. Sci., 2021, 12,613-625DOI: 10.1039/D0SC05311B, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zhe Wang, Rikuo Akisaka, Sohshi Yabumoto, Tatsuo Nakagawa, Sayaka Hatano, Manabu AbeAn extremely long-lived localised singlet diradical with ?-single bonding character is found in a macrocyclic structure that retards the radical–radical coupling reaction by the “stretch and solvent-dynamic effects”.The content of this RSS Feed (c) The Royal Society of Chemistry

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