Hyperconjomer stereocontrol of cationic polyene cyclisations

Org. Biomol. Chem., 2019, 17,8551-8560DOI: 10.1039/C9OB01364D, PaperRobert T. Rodger, Marlowe S. Graham, Christopher S. P. McErleanThe stereochemical outcome of cationic polyene cyclisations of geranylbenzene derivatives is affected by the different reactivity of hyperconjomer intermediates. The synthesis of (±)-taiwaniaquinone G by a cationic polyene cyclisation is described.The content of this RSS Feed (c) The Royal Society of Chemistry

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