A fully diastereoselective oxidation of a mesoionic dipole with triplet molecular oxygen

Org. Biomol. Chem., 2020, Advance ArticleDOI: 10.1039/D0OB01428A, PaperJuan García de la Concepción, Martín Ávalos, José L. Jiménez, Pedro Cintas, Mark E. LightA metal-free oxidation of a mesoionic dipole with atmospheric oxygen triggers a complex cascade reaction through spin intercrossing, as supported by computation, and leading to polycycles with complete diastereoselection.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry

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