Facile Synthesis of [small alpha]-Aminoboronic Acids from Amines and Potassium Acyltrifluoroborates (KATs) via Trifluoroborate-Iminiums (TIMs)

Chem. Sci., 2018, Accepted ManuscriptDOI: 10.1039/C8SC01486H, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Tomoya Shiro, Anne Schuhmacher, Moritz Jackl, Jeffrey W BodeWe report the facile formation of trifluoroborate-iminiums (TIMs) from potassium acyltrifluoroborates (KATs) and the transformation of TIMs to [small alpha]-aminotrifluoroborates by reduction or Grignard addition. Conditions for the hydrolysis of [small alpha]-aminotrifluoroborates...The content of this RSS Feed (c) The Royal Society of Chemistry

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