Base induced isomerisation of a phosphaethynolato-borane: mechanistic insights into boryl migration and decarbonylation to afford a triplet phosphinidene

Chem. Sci., 2020, 11,862-869DOI: 10.1039/C9SC05969E, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Daniel W. N. Wilson, Mauricio P. Franco, William K. Myers, John E. McGrady, Jose M. GoicoecheaWe report on the (tert-butyl)isocyanide-catalysed isomersation of a phosphaethynolato-borane, [B]OCP, to its linkage isomer, a phosphaketenyl-borane, [B]PCO.The content of this RSS Feed (c) The Royal Society of Chemistry

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