Backbone-controlled LUMO energy induces intramolecular C–H activation in ortho-bis-9-borafluorene-substituted phenyl and o-carboranyl compounds leading to novel 9,10-diboraanthracene derivatives

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Chem. Sci., 2022, Advance ArticleDOI: 10.1039/D2SC06057D, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Johannes Krebs, Alena Häfner, Sonja Fuchs, Xueying Guo, Florian Rauch, Antonius Eichhorn, Ivo Krummenacher, Alexandra Friedrich, Lei Ji, Maik Finze, Zhenyang Lin, Holger Braunschweig, Todd B. MarderThe backbone linker for two ortho-bis-(9-borafluorene)s influences the LUMO at the boron centers and the reactivity of the respective compounds.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry

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