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Palladium-Catalyzed Cascade Cyclization of Allenamide with 2-Iodoanilines to Access Functionalized Indoloquinolines

Org. Biomol. Chem., 2022, Accepted ManuscriptDOI: 10.1039/D2OB01770A, CommunicationWenzhe Geng, Hui Wang, Juan XI, Ruonan Jiang, Jintao Guo, Keqiang Jiao, Mengyao Tang, Qing Liu, Lizhi Zhang, Hui LiuA novel and efficient palladium-catalyzed cascade cyclization to indoloquinolines derivates in one pot has been developed by using allenamide derivates and 2-iodoanilines as the key building blocks. The process underwent...The content of this RSS Feed (c) The Royal Society of Chemistry

Redox-neutral rhodium(III)-catalyzed divergent synthesis of tetrasubstituted 1,3-enynes and alkynylated benzofurans

Org. Biomol. Chem., 2022, Accepted ManuscriptDOI: 10.1039/D2OB01800D, PaperXin Gong, Na Yu, Linghui Gu, Zheyu Li, Wenbo Ma, Fei ZhaoWith the assistance of the acetamido directing group (DG), a rhodium-catalyzed C?H alkenylation/DG migration cascade for the synthesis of tetrasubstituted 1,3-enynes from N-phenoxyacetamides and 1,3-diynes has been achieved in this...The content of this RSS Feed (c) The Royal Society of Chemistry

Cytotoxic alkaloids from the twigs and leaves of Cephalotaxus sinensis

Org. Biomol. Chem., 2022, Accepted ManuscriptDOI: 10.1039/D2OB01980A, PaperGuanqun Zhan, Fuxin Zhang, Tao Yang, Kailing Yang, Ruixi Zhou, Yu Zhang, Wenwen Chen, Zhetong Liu, Zengjun GuoTwelve new Cephalotaxus alkaloids (1–12) and nine known analogues (13–21) were isolated and identified from the twigs and leaves of Cephalotaxus sinensis. The structures of new compounds (1–12) were elucidated...The content of this RSS Feed (c) The Royal Society of Chemistry

Selective Reduction of Nitroarenes using Ru/C and CaH2.

Org. Biomol. Chem., 2022, Accepted ManuscriptDOI: 10.1039/D2OB01807A, PaperRamiro Robles-Henríquez, Luis Marcelo Vilches Herrera, Tomás Chávez-Vega, Lucas Lodeiro, Sebastián Gallardo-Fuentes, Susan LührHerein we report an efficient and highly selective method for the reduction of aromatic, heteroaromatic and halo- nitrocompounds using the rapid available and cost-effective Ru/C as catalyst and the unconventional...The content of this RSS Feed (c) The Royal Society of Chemistry

LC-MS Guided Isolation of Hyperpatone A, a polycyclic polyprenylated acylphloroglucinol with an unprecedented 8/6/5/6/5 pentacyclic skeleton from Hypericum patulum

Org. Biomol. Chem., 2022, Accepted ManuscriptDOI: 10.1039/D2OB01851A, PaperChunmao Yuan, Feng Zhang, Yanan Li, Xiaojiang Hao, jue yang, Ping YiHyperpatone A (1), a highly oxidated polycyclic polyprenylated acylphloroglucinol (PPAP), along with a biosynthesized related PPAP (2) was isolated from Hypericum patulum under the guidance of LC-MS investigation. Architecturally, compound...The content of this RSS Feed (c) The Royal Society of Chemistry

Targeting tubulin C-terminal tail by charged small molecules

Org. Biomol. Chem., 2022, Accepted ManuscriptDOI: 10.1039/D2OB01910H, PaperShuo Li, Mattia Mori, Mingyan Yang, soumia elfazazi, Rafael Hortigüela, Peter Chan, Xinyue Feng, April L. Risinger, Zhi-You Yang, María A. Oliva, J. Fernando Diaz, Wei-Shuo FangThe disordered tubulin C-terminal tail (CTT), which possesses higher degree of heterogeneity, is the target for the interaction of many proteins and cellular components. Oppositely to the seven well-described binding...The content of this RSS Feed (c) The Royal Society of Chemistry

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How China's Covid protests are being silenced

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