• user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'ad:0:aurora:http://slickfinder.com/' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = '', created = 1550934207, expire = -1, headers = '', serialized = 0 WHERE cid = 'ad:0:aurora:http://slickfinder.com/' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'counter:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = 'a:2:{s:7:\"subject\";s:7:\"Counter\";s:7:\"content\";s:335:\"<ul id=\"counter\"><li>Site Counter: 8,531,693</li><li>Unique Visitor: 400,349</li><li>Registered Users: 1</li><li>Unregistered Users: 0</li><li>Blocked Users: 0</li><li>Published Nodes: 302,440</li><li>Unpublished Nodes: 6,329</li><li>Server IP: 216.53.213.119</li><li>Your IP: 34.203.28.212</li><li>Since: 2014-07-03 13:09:52</li></ul>\";}', created = 1550934207, expire = -1, headers = '', serialized = 1 WHERE cid = 'counter:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'tribune:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = '', created = 1550934207, expire = -1, headers = '', serialized = 0 WHERE cid = 'tribune:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'tribune:1:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = '', created = 1550934207, expire = -1, headers = '', serialized = 0 WHERE cid = 'tribune:1:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'user:2:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = 'a:2:{s:7:\"subject\";s:9:\"Who\'s new\";s:7:\"content\";s:126:\"<div class=\"item-list\"><ul><li class=\"first last\"><a href=\"/users/admin\" title=\"View user profile.\">admin</a></li>\n</ul></div>\";}', created = 1550934207, expire = -1, headers = '', serialized = 1 WHERE cid = 'user:2:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'book:0:aurora:r.1:http://slickfinder.com/' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = 'a:2:{s:7:\"subject\";s:15:\"Book navigation\";s:7:\"content\";s:0:\"\";}', created = 1550934207, expire = -1, headers = '', serialized = 1 WHERE cid = 'book:0:aurora:r.1:http://slickfinder.com/' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'similar:0:aurora:r.1:http://slickfinder.com/' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = '', created = 1550934207, expire = -1, headers = '', serialized = 0 WHERE cid = 'similar:0:aurora:r.1:http://slickfinder.com/' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
  • user warning: Table './slickfinder_drupal/sessions' is marked as crashed and last (automatic?) repair failed query: SELECT COUNT(sid) AS count FROM sessions WHERE timestamp >= 1550933307 AND uid = 0 in /var/www/vhosts/slickfinder.com/httpdocs/includes/session.inc on line 157.
  • user warning: Table './slickfinder_drupal/sessions' is marked as crashed and last (automatic?) repair failed query: SELECT COUNT(DISTINCT s.uid) FROM sessions s WHERE s.timestamp >= 1550933307 AND s.uid > 0 in /var/www/vhosts/slickfinder.com/httpdocs/modules/user/user.module on line 790.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'simplead_block:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = '', created = 1550934207, expire = -1, headers = '', serialized = 0 WHERE cid = 'simplead_block:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'pagination:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = '', created = 1550934207, expire = -1, headers = '', serialized = 0 WHERE cid = 'pagination:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: SELECT data, created, headers, expire, serialized FROM cache_block WHERE cid = 'recipe:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 25.
  • user warning: Table './slickfinder_drupal/cache_block' is marked as crashed and should be repaired query: UPDATE cache_block SET data = 'a:2:{s:7:\"subject\";s:14:\"Newest Recipes\";s:7:\"content\";b:0;}', created = 1550934207, expire = -1, headers = '', serialized = 1 WHERE cid = 'recipe:0:aurora:r.1' in /var/www/vhosts/slickfinder.com/httpdocs/includes/cache.inc on line 108.

Understanding exo-selective Diels-Alder reactions involving Fischer-type carbene complexes

Org. Biomol. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9OB00132H, PaperJorge Juan Cabrera-Trujillo, Israel FernandezThe factors controlling the selectivity of the Diels-Alder cycloaddition reactions involving Fischer-type carbene complexes and cyclopentadiene have been explored computationally by means of Density Functional Theory calculations. To this end,...The content of this RSS Feed (c) The Royal Society of Chemistry

Na2S promoted reduction of azides in water: Synthesis of pyrazolopyridines in one pot and evaluation of antimicrobial activity

Org. Biomol. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C8OB03171A, PaperKrishnaiah Atmakur, Ashok Kale, Nagaraju Medishetti, sirisha kanugala, Ganesh Kumar CReduction of various azides using Na2S has been accomplished in water and the in situ resulted amine on reaction with various ketones lead to pyrazolo[3,4-b]pyridines in one pot. Thus, a...The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis and characterization of new D-?-A and A-?-D-?-A type oligothiophene derivatives

Org. Biomol. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C8OB03077D, PaperFabiana Pandolfi, Daniele Rocco, Leonardo MattielloIn this work we present a series of newly synthesized conjugated oligothiophene derivatives, with different numbers of central thiophene units, and different donor/acceptor architectures. Electrochemical and spectroscopic data have also...The content of this RSS Feed (c) The Royal Society of Chemistry

An efficient preparation of ?-ketophosphine oxides from alkynylphosphine oxides with benzaldehyde oxime as hydroxide source

Org. Biomol. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9OB00251K, PaperYan-Bo Wang, Lu-Lu Chen, Jing-Wen Zhang, Wan-Wan Yang, Pei Chen, Dan-Yun ChenAn effective and facile transition-metal-free method has been developed for the synthesis of ?-ketophosphine oxides from alkynylphosphine oxides with benzaldehyde oxime as hydroxide surrogate.

Expanding the “minimalist” small molecule tagging approach to different bioactive compounds

Org. Biomol. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C8OB03175D, PaperWenjie Lang, Chaonan Yuan, Biwei Zhu, Sijun Pan, Jian Liu, Jie Luo, Shikun Nie, Qing Zhu, Jun-Seok Lee, Jingyan Ge“Minimalist” Small Molecule Tagging (MSMT) is a promising approach that easily converts bioactive compounds to affinity-based probes (AfBPs) for proteomic studies.

Stereoselective Functionalization of Platensimycin and Platencin by Sulfa-Michael/Aldol Reactions

Org. Biomol. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9OB00324J, PaperLin Qiu, Zhongqing Wen, Yuling Li, Kai Tian, Youchao Deng, Ben Shen, Yanwen Duan, Yong HuangBioinspired sulfa-Michael/aldol cascade reactions have been developed for the semisynthesis of sulfur-containing heterocyclic derivatives of platensimycin and platencin, with three newly-formed contiguous stereogenic centers.

Cinnamic acid derivatives as promising building blocks for advanced polymers: synthesis, properties and applications

Polym. Chem., 2019, Accepted ManuscriptDOI: 10.1039/C9PY00121B, Review ArticleAna Clotilde Fonseca, Mafalda Lima, Andreia F. Sousa, Armando Silvestre, Jorge Coelho, Arménio Coimbra SerraCinnamic acid (CA) and its hydroxy-derivatives are aromatic building blocks whose structural peculiarities (unsaturation, hydroxylic and/or carboxylic group) drove them to a prominent position in polymer science.

Cross-linking of shrimp tropomyosin catalyzed by transglutaminase and tyrosinase produce hypoallergens for potential immunotherapy

Food Funct., 2019, Accepted ManuscriptDOI: 10.1039/C9FO00046A, PaperYanbo Wang, Saiqiao Ni, Chong Wang, xiuting li, Linglin FuTropomyosin (TM) is the major allergen in shellfish, which causes severe food allergy worldwide, and shows wide cross-reactivity in different species. Transglutaminase (TG) and tyrosinase (Tyr) are protein modification enzymes...The content of this RSS Feed (c) The Royal Society of Chemistry

Peptides from chicken processing by-product inhibit DPP-IV and promote cellular glucose uptake: potential ingredients for T2D management

Food Funct., 2019, Accepted ManuscriptDOI: 10.1039/C8FO02450B, PaperRita de Cássia Lemos Lima, Ragnhild Stenberg Berg, Sissel Beate Rønning, Nils Kristian Afseth, Svein Halvor Halvor Knutsen, Dan Staerk, Sileshi WubshetInhibition of dipeptidyl peptidase IV (DPP-IV) and stimulation of muscle glucose uptake are two of the key strategies for management of type-2-diabetes (T2D).

Zeaxanthin promotes mitochondrial biogenesis and adipocyte browning via AMPK?1 activation

Food Funct., 2019, Accepted ManuscriptDOI: 10.1039/C8FO02527D, PaperMeihong Liu, Mingzhu Zheng, Dan Cai, Jiahan Xie, Zhibo Jin, Huimin Liu, Jingsheng LiuZeaxanthin (ZEA), a type of oxygenated carotenoid with strong antioxidant activity, has previously been found to exhibit an anti-lipogenesis effect. In the present study, we investigated the effect of ZEA...The content of this RSS Feed (c) The Royal Society of Chemistry

Arsenal face Rennes & Chelsea play Dynamo Kiev in Europa League

Arsenal will play French side Rennes and Chelsea are drawn against Ukraine's Dynamo Kiev in the last 16 of the Europa League.

Arlo Ultra, hands-on: A premium security camera with expansion potential

The Arlo Ultra delivers high-quality video recording and added features like an integrated siren and spotlight. With the SmartHub, it can form the basis of a wider security system.

Brexit: Theresa May warned dozens of Tories could rebel over no-deal

Downing Street says talks continue "at pace" to get the changes to Theresa May's Brexit deal demanded by MPs.

Six Nations: Wales v England - watch some of the greatest moments from past matches

As Wales take on England in the Six Nations, watch some of the greatest moments, including Gavin Henson's tackle on Matthew Tait and James Haskell hitting the post.

Seven-time Challenge Cup winners Widnes go into administration and face liquidation

Widnes Vikings go into administration and face liquidation if suitable investment is not found by next week.

Venezuela crisis: Maduro closes border with Brazil

President Maduro acts as opposition supporters defy attempts to stop them bringing in foreign aid.

Nigerian elections: Voters taken through danger zone

Witnesses tell the BBC they were taken home from refugee camps despite the threat from Boko Haram.

Automate everything: Welcome to the era of DIY robotics

Falling sensor prices, rapid prototyping, the abundance of cheap microprocessors, and a supportive community of makers have all contributed to enthusiasts creating armies of clever robots.

Free Galaxy Buds with Galaxy S10 preorders

Samsung’s unpacked event saw the launch of the Galaxy S10 and Samsung Fold. You’ll be able to get your hands on a free pair of Samsung Buds when you preorder a Galaxy S10.

Russian cemetery gang leaves widow with body out in cold

Told to pay a huge funeral fee, a widow in Samara protested with a coffin outside parliament.

Galaxy S10E, S10, and S10 Plus: How to pre-order and get the best deal

Here's how much Samsung's new phones cost, how to pre-order or buy them online, and all the best deals.

Three Carpet Cleaning Secrets to Keep Your Carpet Looking It’s Best

Keeping your carpets clean can be a rather arduous process –
especially if you have kids running around. They sometimes create more mess
than the family dog! So, we at thought we’d offer our top tips on how to keep
your carpets clean.

Moto G7 Play review

The Moto G7 Play isn't perfect, but it's a contender for the title of the best budget smartphone. Find out why in our review.

Syria war: US to leave 200 troops for peacekeeping after withdrawal

The announcement follows fierce criticism of President Donald Trump's decision to withdraw US troops.

In Search of Life's Origins, Japan's Hayabusa 2 Spacecraft Lands on an Asteroid

The mission to Asteroid Ryugu could return samples of the space rock to Earth in 2020

-- Read more on ScientificAmerican.com

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